FM21_12687
XXI International Congress of Theoretical and Applied Mechanics
Warsaw, Poland, August 15-21, 2004

Convective Heat and Mass Transport in Novel Bridgman Configurations for Cadmium Zinc Telluride Growth

Andrew Yeckel, Jeffrey J. Derby
Dept. of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, USA


We are studying the influences of convection on heat and mass transfer in vertical Bridgman (VB) systems used to grow cadmium zinc telluride (CZT), a ternary compound which is susceptible to constitutional supercooling. We have constructed transport models of two novel VB configurations. A top-seeded configuration has a destabilizing temperature gradient in the melt. The flows in this configuration are far more intense than occur in the stabilized bottom-seeded VB configuration. Better mixing reduces radial segregation for doped-semiconductor melts, results that we expect will extend to CZT melts. Interface shapes remain unfavorably concave, however. An alternative is a bottom-seeded VB system with submerged heater, which gives superior control of interface shape, but which has poor lateral mixing. This alternative requires active control to maintain a constant gap between the interface and the heater. We will compare these systems in terms of interface shape, morphological stability, segregation behavior, and thermal stresses.



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